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AP Chemistry – AP Chemistry – Mistake Review 

Mistake Review – Focus on Weak Point

  • Do NOT rush

  • Say reasoning out loud

  • Goal: never miss these again

PART 1: Equilibrium ( #1 Weak Area)

Question 1

If Q < K, the reaction will:

A. shift left
B. shift right
C. stop
D. no change

... Correct Answer: B Why: Q < K means not enough products → reaction moves forward. Common Mistake: Confusing QK. Fix It: Q K → LEFT

Question 2

If Q > K, the reaction will:

A. shift right
B. shift left
C. stop
D. no change

... Correct Answer: B Why: Too many products → system shifts left. Fix It: Too much product → go backward

Question 3

For:
N₂ + 3H₂ ⇌ 2NH₃

If pressure increases:

A. shift left
B. shift right
C. no change
D. depends

... Correct Answer: B Why: Left = 4 moles gas Right = 2 moles gas → shift to fewer moles Fix It: High pressure → fewer gas molecules

Question 4

Removing product causes equilibrium to:

A. shift left
B. shift right
C. no change
D. stop

... Correct Answer: B Why: System tries to replace removed product. Fix It: Remove product → make more product

Question 5

For an exothermic reaction, increasing temperature:

A. shifts right
B. shifts left
C. no change
D. increases K

... Correct Answer: B Why: Heat is product → adding heat shifts left. Fix It: Exo + heat → LEFT Endo + heat → RIGHT

Question 6

Which factor changes K?

A. pressure
B. concentration
C. catalyst
D. temperature

... Correct Answer: D Why: Only temperature changes equilibrium constant. Fix It: Only TEMP affects K

PART 2: Acid–Base Precision (#2)

Question 7

What is pH of 1×10⁻⁵ M HCl?

A. 3
B. 4
C. 5
D. 6

... Correct Answer: C Why: pH = -log(10⁻⁵) = 5 Fix It: Exponent = pH

Question 8

Which has highest pH?

A. 1 M acid
B. 0.1 M acid
C. 0.01 M acid
D. 0.001 M acid

... Correct Answer: D Why: More dilute → fewer H⁺ → higher pH Fix It: Dilution ↑ → pH ↑

Question 9

Adding acid to a buffer will:

A. big decrease
B. small decrease
C. increase pH
D. no change

... Correct Answer: B Why: Buffer resists change. Common Mistake: Thinking big pH change. Fix It: Buffer = small change only

Question 10

Diluting an acid:

A. lowers pH
B. raises pH
C. no change
D. neutralizes

... Correct Answer: B Why: [H⁺] decreases → pH increases Fix It: Dilution = less acidic

FINAL 10 QUESTIONS (AP 5-Level Training)

Question 11(Q vs K Trap)

For a reaction, Q = 0.5 and K = 5. What happens?

A. shift left
B. shift right
C. no change
D. stop

... Correct Answer: B Why: Q < K → not enough product → shift right. Trap: Students reverse Q and K. Fix It: Q K → LEFT

Question 12(Exo vs Endo Trap)

For an exothermic reaction, increasing temperature:

A. increases K
B. decreases K
C. no change
D. shifts right

... Correct Answer: B Why: Heat is product → adding heat shifts left → less product → K decreases. Trap: Students think temp always increases K. Fix It: Exo → temp ↑ → K ↓ Endo → temp ↑ → K ↑

Question 13(Pressure + Moles)

If pressure increases, equilibrium shifts toward:

A. more gas moles
B. fewer gas moles
C. solids
D. liquids

... Correct Answer: B Why: System reduces pressure by lowering gas particles. Trap: Forgetting to COUNT moles. Fix It: Pressure ↑ → fewer moles

Question 14(Catalyst Trap)

Adding a catalyst will:

A. increase K
B. shift equilibrium
C. speed reaction
D. increase products

... Correct Answer: C Why: Catalyst lowers activation energy only. Trap: Thinking equilibrium shifts. Fix It: Catalyst = faster ONLY

Question 15(K Expression Trap)

Which is included in K?

A. solids
B. liquids
C. gases
D. none

... Correct Answer: C Why: Only (g) and (aq) included. Trap: Students include everything. Fix It: Ignore solids & liquids

Question 16(pH Quick Calculation)

What is pH of 1×10⁻⁶ M HCl?

A. 4
B. 5
C. 6
D. 7

... Correct Answer: C Why: pH = -log(10⁻⁶) = 6 Trap: Overthinking log. Fix It: Exponent = pH

Question 17(pH vs Strength Trap)

Which is MOST acidic?

A. 0.1 M HCl
B. 0.01 M HCl
C. 0.001 M HCl
D. 1 M HCl

... Correct Answer: D Why: Highest concentration → most H⁺ → lowest pH. Trap: Confusing dilution. Fix It: More concentrated → more acidic

Question 18(Buffer Trap)

A buffer resists pH change because:

A. it is neutral
B. it reacts with added acid/base
C. it has high pH
D. it stops reactions

... Correct Answer: B Why: Buffer components neutralize added acid/base. Trap: Thinking buffer = neutral. Fix It: Buffer = reacts to stabilize

Question 19(Dilution Trap)

Diluting a base will:

A. increase pH
B. decrease pH
C. no change
D. neutralize

... Correct Answer: B Why: [OH⁻] decreases → pH decreases. Trap: Mixing acid/base logic. Fix It: Dilute base → less basic

Question 20(Equilibrium Concept)

At equilibrium:

A. reaction stops
B. forward = reverse rate
C. equal concentrations
D. no movement

... Correct Answer: B Why: Dynamic equilibrium → reactions still occur. Trap: Thinking reaction stops. Fix It: Rates equal, not amounts

PART 3: FRQ Precision (CRITICAL FOR 5)

FRQ 1

Explain effect of catalyst

... Perfect Answer: A catalyst lowers activation energy, increasing the rate of both forward and reverse reactions equally. It does not change the equilibrium constant or equilibrium position.

FRQ 2

Explain equilibrium shift with temperature (endothermic)

... Perfect Answer: In an endothermic reaction, heat acts as a reactant. Increasing temperature adds heat, shifting equilibrium to the right to produce more products.

FRQ 3

Explain dilution effect

... Perfect Answer: Dilution decreases the concentration of H⁺ ions, which increases the pH of the solution.

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